In a new study published in Langmuir, the researchers confirmed that modifying the surface properties of solar panels may greatly reduce the amount of dust remaining on the surface, and significantly increase the potential of solar energy harvesting applications in the desert.
Dust adhesion on solar panels is a major challenge to energy harvesting through photovoltaic cells and solar thermal collectors. New solutions are necessary to maintain maximum collection efficiency in high dust density areas such as the Negev desert in Israel.
"In nature, we observe that the lotus leaf remains dust and pathogen free due to its nanotextured surface, and a thin wax, hydrophobic coating that repels water," says Tabea Heckenthaler, a master's student from Düsseldorf Germany at the BGU Zuckerberg Institute for Water Research, Jacob Blaustein Institutes for Desert Research. "In the desert, dust accumulates on the surface of solar cells and it's labor-intensive to clean them constantly, so we're trying to mimic this behavior on a solar cell."
The researchers explored the effect of modifying a silicon substrate (Si), a semiconductor used in photovoltaic cells, to mimic the self-cleaning properties of the lotus leaf, as water rolls down the leaves and removes contamination.
It is known that superhydrophobicity reduces the friction between water droplets and the surface, thus allowing water drops to slide clean particles from surfaces. However, the forces that attach and detach particles from surfaces during the self-cleaning mechanism and the effect of nanotextures on these forces are not fully understood.
To shed light on these forces and the effect of nanotexture on them, the researchers prepared four silicon-based samples relevant to solar panels: (1) smooth hydrophillic (2) nanotextured hydrophilic surfaces and (3) smooth hydrophobic (4) nanotextured hydrophobic surfaces. This was achieved by wet-chemically etching the surface to create nanowires on the surface, and additionally applying a hydrophobic coating.
Particle removal increased from 41 percent on hydrophilic smooth Si wafers to 98 percent on superhydrophobic Si-based nanotextured surfaces. The researchers confirmed these results by measuring the adhesion of a micron-sized particle to the flat and nanotextured substrate using an atomic force microscope. They found that the adhesion in water is reduced by a factor of 30.
"We determined that the reason for the increased particle removal is not low friction between the droplets and the superhydrophobic surfaces," Heckenthaler says. "Rather, it is the increase in the forces that can detach particles from the surfaces. The experimental methods we used and the criterion for particle removal we derived can be implemented to engineer self-cleaning surfaces exhibiting different chemistries and/or textures."
